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The Nose Knows,
But So Does the Gas Chromatograph
One of the greatest tools for analyzing
a scent's components is the gas chromatograph (GC). For perfumers,
the GC is perhaps the most important invention—days of organic chemistry
research are now performed in a few hours. How does it work? Even
Jolique can't understand all the particulars, but one chemist explained
it to her like this:
First, imagine a long, thin tube with
one end connected to a detection device similar to an EKG or a lie
detector, called a mass spectrometer (MS). Flowing through the tube
is an inert "carrier gas," such as helium or nitrogen, as well as
millions of oil-coated beads, each about the size of a grain of
sand. Now imagine that a bunch of odor molecules—lemon and
hyacinth, for example—are blown through the tube. (Remember: these
are lemon and hyacinth molecules—they can't be seen with
the naked eye.) The carrier gas "carries" each of these molecules
through the tube, but because the oily beads obstruct their passage
somewhat, the molecules are slow to reach the end of the tube. Also,
some of the molecules are heavier than others, and therefore move
even more slowly. The amount of time it takes each molecule to move
from one end of the tube to the other is recorded on the EKG-like
printout. These time measurements are unique to each type of molecule:
lemon odor molecules travel at a rate that is different from lavender's
rate. So by reading the amount of time it takes for an odor to travel
along the tube, you can tell what kind of odor it is. These printouts
are the blueprints to a scent's entire chemical make-up. They are
as closely-guarded by perfumers as is the Hope Diamond by the National
Gallery!
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Above: The fragrant hyacinth |